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            将本页翻译成中文
            您现在的位置:首页> 外文会议>Conference on Advanced Laser Technologies 2005 pt.2; 20050903-06; Tianjin(CN) >文献详情

            【24h】 Asymmetric interactions in gas phase clusters

            【摘要】Molecular clusters are non covalent aggregates recognized as a new state of matter, whose properties arc neither those of the gas-phase isolated partners nor those of their condensed phases. Molecular clusters have proved to be ideal systems for modeling molecular recognition phenomena, and their applications in many scientific fields interlocking the physical and life sciences are now well assessed .In the last few years, it has become possible, through the use of advanced laser techniques, to study the single interactions acting between individual components of a cluster without the influence of the solvent The studies were carried out developing laser spcctroscopic methodologies, capable of characterizing molecular clusters and probing the chemical bond breaking and forming on an extremely short time scale. This contribution deals with chiral recognition of molecules and clusters of biological interest in the gas phase through the application of the laser resolved mass spectrometric Resonant Two Photon Ionization technique (R2PI). The measurement of the spectroscopic shifts and of the fragmentation thresholds of diastcromeric clusters allows the determination of the nature of the interactions which control the formation of biological material and affect their stability and reactivity.

            【会议名称】 Conference on Advanced Laser Technologies 2005 pt.2; 20050903-06; Tianjin(CN)

            【会议地点】Tianjin(CN)

            【作者】A. Giardini;A. Paladini;S. Piccirillo;D. Catone;F. Rondino;M. Satta;M. Speranza;

            【作者单位】Dip. di Chimica, Universita degli Studi di Roma 'La Sapienza', pl. A. Moro 5, 00185 Rome, Italy;

            【会议组织】

            【会议召开年】2005

            【页码】P.63441X.1-63441X.8

            【总页数】8

            【原文格式】PDF

            【正文语种】eng

            【中图分类】TN24;

            【关键词】laser spectroscopy;mass spectrometry;chiral discrimination;supersonic beam;clusters;microsolvation;

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